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A borane-mediated palladium-catalyzed reductive allylic alkylation of α,β-unsaturated carbonyl compounds
The development of the palladium-catalyzed allylic alkylation of in situ generated boron enolates via tandem 1,4-hydroboration is reported. Investigation of the reaction revealed insights into specific catalyst electronic features as well as a profound leaving group effect that proved crucial for ac...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
The Royal Society of Chemistry
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8150111/ https://ncbi.nlm.nih.gov/pubmed/34123302 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05970a |
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