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Controllable double CF(2)-insertion into sp(2) C–Cu bond using TMSCF(3): a facile access to tetrafluoroethylene-bridged structures

A highly efficient method for controllable double CF(2)-insertion into pentafluorophenylcopper species using TMSCF(3) as difluoromethylene source has been developed. The newly generated fluoroalkylcopper(i) species, C(6)F(5)CF(2)CF(2)Cu, shows good reactivity towards a myriad of structurally diverse...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Xie, Qiqiang, Zhu, Ziyue, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: The Royal Society of Chemistry 2019
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC8133001/
https://ncbi.nlm.nih.gov/pubmed/34040722
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05018c
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