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Exploring Cu/Al cluster growth and reactivity: from embryonic building blocks to intermetalloid, open-shell superatoms

Cluster growth reactions in the system [Cu(5)](Mes)(5) + [Al(4)](Cp*)(4) (Mes = mesitylene, Cp* = pentamethylcyclopentadiene) were explored and monitored by in situ LIFDI-MS and (1)H-NMR. Feedback into experimental design allowed for an informed choice and precise adjustment of reaction conditions a...

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Publicat a:Chem Sci
Autors principals: Schütz, Max, Gemel, Christian, Muhr, Maximilian, Jandl, Christian, Kahlal, Samia, Saillard, Jean-Yves, Fischer, Roland A.
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2021
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8132940/
https://ncbi.nlm.nih.gov/pubmed/34040734
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00268f
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