Synthesis and structural characterization of inverse-coordination clusters from a two-electron superatomic copper nanocluster

We have synthesized and structurally characterized a series of centred cuboctahedral copper clusters, namely [Cu(13){S(2)CNR(2)}(6){C[triple bond, length as m-dash]CR′}(4)](PF(6)), 1a–d (where a: R = (n)Bu, R′ = CO(2)Me; b: R = (n)Bu, R′ = CO(2)Et; c: R = (i)Pr, R′ = CO(2)Et; d: R = (n)Pr, R′ = 3,5-...

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Bibliografski detalji
Izdano u:Chem Sci
Glavni autori: Chakrahari, Kiran Kumarvarma, Silalahi, Rhone P. Brocha, Liao, Jian-Hong, Kahlal, Samia, Liu, Yu-Chiao, Lee, Jyh-Fu, Chiang, Ming-Hsi, Saillard, Jean-Yves, Liu, C. W.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2018
Teme:
Chemistry
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6115619/
https://ncbi.nlm.nih.gov/pubmed/30310611
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01508b
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