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Embryonic brass: pseudo two electron Cu/Zn clusters

The isoelectronic M(7) clusters [Cu(3)Zn(4)](Cp*)(5) (1) and {[Cu(2)Zn(5)](Cp*)(5)}(+) (2) are described. While 1 can be isolated only as a minor side product from the reaction of Cu(CH(3)CO(2)) with equimolar amounts of [Zn(2)Cp*(2)] with the trigonal cluster [CuZn(2)](Cp*)(3) as the major product,...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Banh, Hung, Hornung, Julius, Kratz, Thilo, Gemel, Christian, Pöthig, Alexander, Gam, Franck, Kahlal, Samia, Saillard, Jean-Yves, Fischer, Roland A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6301272/
https://ncbi.nlm.nih.gov/pubmed/30647885
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03902j
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