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Generating Stereodiversity: Diastereoselective Fluorination and Highly Diastereoselective Epimerization of α-Amino Acid Building Blocks
Diastereoselective fluorination of N-Boc (R) and (S)-2,2-dimethyl-4-((arylsulfonyl)methyl)oxazolidines, and a previously unknown diastereoselective epimerization at the fluorine-bearing carbon atom alpha to the sulfone was realized. Diastereoselectivities of both reactions were excellent for benzoth...
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| Publicado no: | Org Lett |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8117975/ https://ncbi.nlm.nih.gov/pubmed/29856640 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b01358 |
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