Iterative Exponential Growth of Oxygen-Linked Aromatic Polymers Driven by Nucleophilic Aromatic Substitution Reactions

This work presents the first transition metal-free synthesis of oxygen-linked aromatic polymers by integrating iterative exponential polymer growth (IEG) with nucleophilic aromatic substitution (S(N)Ar) reactions. Our approach applies methyl sulfones as the leaving groups, which eliminate the need f...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Front Chem
Prif Awduron: Jaynes, Tyler J., Sharafi, Mona, Campbell, Joseph P., Bocanegra, Jessica, McKay, Kyle T., Little, Kassondra, Osadchey Brown, Reilly, Gray, Danielle L., Woods, Toby J., Li, Jianing, Schneebeli, Severin T.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Frontiers Media S.A. 2021
Pynciau:
Chemistry
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC8113702/
https://ncbi.nlm.nih.gov/pubmed/33996739
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2021.620017
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