Iterative Exponential Growth of Oxygen-Linked Aromatic Polymers Driven by Nucleophilic Aromatic Substitution Reactions

This work presents the first transition metal-free synthesis of oxygen-linked aromatic polymers by integrating iterative exponential polymer growth (IEG) with nucleophilic aromatic substitution (S(N)Ar) reactions. Our approach applies methyl sulfones as the leaving groups, which eliminate the need f...

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Detalhes bibliográficos
Publicado no:Front Chem
Main Authors: Jaynes, Tyler J., Sharafi, Mona, Campbell, Joseph P., Bocanegra, Jessica, McKay, Kyle T., Little, Kassondra, Osadchey Brown, Reilly, Gray, Danielle L., Woods, Toby J., Li, Jianing, Schneebeli, Severin T.
Formato: Artigo
Idioma:Inglês
Publicado em: Frontiers Media S.A. 2021
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8113702/
https://ncbi.nlm.nih.gov/pubmed/33996739
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2021.620017
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