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A Streamlined Regenerative Glycosylation Reaction: Direct, Acid-Free Activation of Thioglycosides

Our group has previously reported that 3,3-difluoroxindole (HOFox) is able to mediate glycosylations via intermediacy of OFox imidates. Thioglycoside precursors were first converted into the corresponding glycosyl bromides that were then converted into the OFox imidates in the presence of Ag(2)O fol...

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Dettagli Bibliografici
Pubblicato in:Chemistry
Autori principali: Escopy, Samira, Singh, Yashapal, Stine, Keith J., Demchenko, Alexei V.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8111381/
https://ncbi.nlm.nih.gov/pubmed/32804435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003479
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