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Koenigs–Knorr Glycosylation Reaction Catalyzed by Trimethylsilyl Trifluoromethanesulfonate

The discovery that traditional silver(I)-oxide-promoted glycosidations of glycosyl bromides (Koenigs–Knorr reaction) can be greatly accelerated in the presence of catalytic trimethylsilyl trifluoromethanesulfonate (TMSOTf) is reported. The reaction conditions are very mild that allowed for maintaini...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Singh, Yashapal, Demchenko, Alexei V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6522226/
https://ncbi.nlm.nih.gov/pubmed/30407673
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201805527
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