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Koenigs–Knorr Glycosylation Reaction Catalyzed by Trimethylsilyl Trifluoromethanesulfonate

The discovery that traditional silver(I)-oxide-promoted glycosidations of glycosyl bromides (Koenigs–Knorr reaction) can be greatly accelerated in the presence of catalytic trimethylsilyl trifluoromethanesulfonate (TMSOTf) is reported. The reaction conditions are very mild that allowed for maintaini...

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Vydáno v:Chemistry
Hlavní autoři: Singh, Yashapal, Demchenko, Alexei V.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2018
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6522226/
https://ncbi.nlm.nih.gov/pubmed/30407673
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201805527
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