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A Streamlined Regenerative Glycosylation Reaction: Direct, Acid-Free Activation of Thioglycosides

Our group has previously reported that 3,3-difluoroxindole (HOFox) is able to mediate glycosylations via intermediacy of OFox imidates. Thioglycoside precursors were first converted into the corresponding glycosyl bromides that were then converted into the OFox imidates in the presence of Ag(2)O fol...

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Bibliografske podrobnosti
izdano v:Chemistry
Main Authors: Escopy, Samira, Singh, Yashapal, Stine, Keith J., Demchenko, Alexei V.
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC8111381/
https://ncbi.nlm.nih.gov/pubmed/32804435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003479
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