A Synthetically Generated LFe(IV)OH(n) Complex

High-valent Fe–OH species are important intermediates in hydroxylation chemistry. Such complexes have been implicated in mechanisms of oxygen-activating enzymes and have thus far been observed in Compound II of sulfur-ligated heme enzymes like cytochrome P450. Attempts to synthetically model such sp...

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Bibliografiska uppgifter
I publikationen:Inorg Chem
Huvudupphovsmän: Weitz, Andrew C., Mills, Matthew R., Ryabov, Alexander D., Collins, Terrence J., Guo, Yisong, Bominaar, Emile L., Hendrich, Michael P.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2019
Ämnen:
Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC8059104/
https://ncbi.nlm.nih.gov/pubmed/30667223
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b03200
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