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Structurally Modelling the 2‐His‐1‐Carboxylate Facial Triad with a Bulky N,N,O Phenolate Ligand
We present the synthesis and coordination chemistry of a bulky, tripodal N,N,O ligand, Im(Ph2)NNO (tBu) (L), designed to model the 2‐His‐1‐carboxylate facial triad (2H1C) by means of two imidazole groups and an anionic 2,4‐di‐tert‐butyl‐subtituted phenolate. Reacting K‐L with MCl(2) (M = Fe, Zn) aff...
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| 出版年: | Chemistry |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2021
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8048785/ https://ncbi.nlm.nih.gov/pubmed/33326655 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004633 |
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