Superalkali–Alkalide Interactions and Ion Pairing in Low-Polarity Solvents

[Image: see text] The nature of anionic alkali metals in solution is traditionally thought to be “gaslike” and unperturbed. In contrast to this noninteracting picture, we present experimental and computational data herein that support ion pairing in alkalide solutions. Concentration dependent ionic...

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Publicat a:J Am Chem Soc
Autors principals: Riedel, René, Seel, Andrew G., Malko, Daniel, Miller, Daniel P., Sperling, Brendan T., Choi, Heungjae, Headen, Thomas F., Zurek, Eva, Porch, Adrian, Kucernak, Anthony, Pyper, Nicholas C., Edwards, Peter P., Barrett, Anthony G. M.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2021
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8028040/
https://ncbi.nlm.nih.gov/pubmed/33660507
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c00115
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