Superalkali–Alkalide Interactions and Ion Pairing in Low-Polarity Solvents

[Image: see text] The nature of anionic alkali metals in solution is traditionally thought to be “gaslike” and unperturbed. In contrast to this noninteracting picture, we present experimental and computational data herein that support ion pairing in alkalide solutions. Concentration dependent ionic...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Riedel, René, Seel, Andrew G., Malko, Daniel, Miller, Daniel P., Sperling, Brendan T., Choi, Heungjae, Headen, Thomas F., Zurek, Eva, Porch, Adrian, Kucernak, Anthony, Pyper, Nicholas C., Edwards, Peter P., Barrett, Anthony G. M.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2021
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8028040/
https://ncbi.nlm.nih.gov/pubmed/33660507
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c00115
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