PQQ‐dependent Dehydrogenase Enables One‐pot Bi‐enzymatic Enantio‐convergent Biocatalytic Amination of Racemic sec‐Allylic Alcohols

The asymmetric amination of secondary racemic allylic alcohols bears several challenges like the reactivity of the bi‐functional substrate/product as well as of the α,β‐unsaturated ketone intermediate in an oxidation‐reductive amination sequence. Heading for a biocatalytic amination cascade with a m...

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Publicat a:ChemCatChem
Autors principals: Gandomkar, Somayyeh, Rocha, Raquel, Sorgenfrei, Frieda A., Montero, Lía Martínez, Fuchs, Michael, Kroutil, Wolfgang
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986696/
https://ncbi.nlm.nih.gov/pubmed/33777250
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.202001707
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