Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me(3)P)(2)(Ph(3)P)Rh≡E‐Ar*] (E=Sn, Pb)

Tetrylidynes [(Me(3)P)(2)(Ph(3)P)Rh≡SnAr*] (10) and [(Me(3)P)(2)(Ph(3)P)Rh≡PbAr*] (11) are accessed for the first time via dehydrogenation of dihydrides [(Ph(3)P)(2)RhH(2)SnAr*] (3) and [(Ph(3)P)(2)RhH(2)PbAr*] (7) (Ar*=2,6‐Trip(2)C(6)H(3), Trip=2,4,6‐triisopropylphenyl), respectively. Tin dihydride...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Widemann, Max, Eichele, Klaus, Schubert, Hartmut, Sindlinger, Christian P., Klenner, Steffen, Pöttgen, Rainer, Wesemann, Lars
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986155/
https://ncbi.nlm.nih.gov/pubmed/33438371
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015725
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