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Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me(3)P)(2)(Ph(3)P)Rh≡E‐Ar*] (E=Sn, Pb)
Tetrylidynes [(Me(3)P)(2)(Ph(3)P)Rh≡SnAr*] (10) and [(Me(3)P)(2)(Ph(3)P)Rh≡PbAr*] (11) are accessed for the first time via dehydrogenation of dihydrides [(Ph(3)P)(2)RhH(2)SnAr*] (3) and [(Ph(3)P)(2)RhH(2)PbAr*] (7) (Ar*=2,6‐Trip(2)C(6)H(3), Trip=2,4,6‐triisopropylphenyl), respectively. Tin dihydride...
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| Publicat a: | Angew Chem Int Ed Engl |
|---|---|
| Autors principals: | , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
John Wiley and Sons Inc.
2021
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7986155/ https://ncbi.nlm.nih.gov/pubmed/33438371 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015725 |
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