Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn(10)](3–), [Rh@Sn(12)](3–), [Rh(2)@Sn(17)](6–) and the first triply-fused stannide, [Rh(3)@Sn(24)](5–)

Through relatively subtle changes in reaction conditions, we have been able to isolate four distinct Rh/Sn cluster compounds, [Rh@Sn(10)](3–), [Rh@Sn(12)](3–), [Rh(2)@Sn(17)](6–) and [Rh(3)@Sn(24)](5–), from the reaction of K(4)Sn(9) with [(COE)(2)Rh(μ-Cl)](2)(COE = cyclooctene). The last of these h...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Liu, Chao, Jin, Xiao, Li, Lei-Jiao, Xu, Jun, McGrady, John E., Sun, Zhong-Ming
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6472436/
https://ncbi.nlm.nih.gov/pubmed/31057766
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03948h
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