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Multi‐Talented Gallaphosphene for Ga−P−Ga Heteroallyl Cation Generation, CO(2) Storage, and C(sp(3))−H Bond Activation
Gallaphosphene L(Cl)GaPGaL (2; L=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2)), which is synthesized by reaction of LGa(Cl)PCO (1) with LGa, reacts with [Na(OCP)(dioxane)(2.5)] to LGa(OCP)PGaL (3), whereas chloride abstraction with LiBAr(F) (4) yields [LGaPGaL][BAr(F) (4)] (4; BAr(F) (4)=B(C(6)F(5))(4)). 4 re...
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| Publicado no: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7986129/ https://ncbi.nlm.nih.gov/pubmed/33368922 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014381 |
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