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Formal Enone α-Arylation via I(III)-Mediated Aryl Migration/Elimination
[Image: see text] A formal enone α-arylation is described. This metal-free transformation relies on the I(III)-mediated skeletal reorganization of silyl enol ethers and features mild conditions, good yields, and high stereoselectivities for β-substituted enones.
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| Veröffentlicht in: | Org Lett |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American
Chemical Society
2021
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7985840/ https://ncbi.nlm.nih.gov/pubmed/33635665 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.1c00251 |
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