Isolation and characterization of a covalent Ce(IV)-Aryl complex with an anomalous (13)C chemical shift

The synthesis of bona fide organometallic Ce(IV) complexes is a formidable challenge given the typically oxidizing properties of the Ce(IV) cation and reducing tendencies of carbanions. Herein, we report a pair of compounds comprising a Ce(IV) − C(aryl) bond [Li(THF)(4)][Ce(IV)(κ(2)-ortho-oxa)(MBP)(...

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Udgivet i:Nat Commun
Main Authors: Panetti, Grace B., Sergentu, Dumitru-Claudiu, Gau, Michael R., Carroll, Patrick J., Autschbach, Jochen, Walsh, Patrick J., Schelter, Eric J.
Format: Artigo
Sprog:Inglês
Udgivet: Nature Publishing Group UK 2021
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7969749/
https://ncbi.nlm.nih.gov/pubmed/33731719
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-21766-4
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