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Similar ligand–metal bonding for transition metals and actinides? 5f(1) U(C(7)H(7))(2)(–)versus 3d(n) metallocenes

U(C(7)H(7))(2)(–) is a fascinating 5f(1) complex whose metal–ligand bonding was assigned in the literature as being very similar to 3d(7) cobaltocene, based on a crystal-field theoretical interpretation of the experimental magnetic resonance data. The present work provides an in-depth theoretical st...

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Vydáno v:Chem Sci
Hlavní autoři: Sergentu, Dumitru-Claudiu, Gendron, Frédéric, Autschbach, Jochen
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6063092/
https://ncbi.nlm.nih.gov/pubmed/30123484
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05373h
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