Octacarbonyl Ion Complexes of Actinides [An(CO)(8)](+/−) (An=Th, U) and the Role of f Orbitals in Metal–Ligand Bonding

The octacarbonyl cation and anion complexes of actinide metals [An(CO)(8)](+/−) (An=Th, U) are prepared in the gas phase and are studied by mass‐selected infrared photodissociation spectroscopy. Both the octacarbonyl cations and anions have been characterized to be saturated coordinated complexes. Q...

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Bibliographic Details
Published in:Chemistry
Main Authors: Chi, Chaoxian, Pan, Sudip, Jin, Jiaye, Meng, Luyan, Luo, Mingbiao, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2019
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6772027/
https://ncbi.nlm.nih.gov/pubmed/31276242
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902625
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