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Octacarbonyl Ion Complexes of Actinides [An(CO)(8)](+/−) (An=Th, U) and the Role of f Orbitals in Metal–Ligand Bonding
The octacarbonyl cation and anion complexes of actinide metals [An(CO)(8)](+/−) (An=Th, U) are prepared in the gas phase and are studied by mass‐selected infrared photodissociation spectroscopy. Both the octacarbonyl cations and anions have been characterized to be saturated coordinated complexes. Q...
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| 出版年: | Chemistry |
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| 主要な著者: | , , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6772027/ https://ncbi.nlm.nih.gov/pubmed/31276242 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902625 |
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