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Group 6 Hexacarbonyls as Ligands for the Silver Cation: Syntheses, Characterization, and Analysis of the Bonding Compared with the Isoelectronic Group 5 Hexacarbonylates
The syntheses of the two novel complexes [Ag{Mo/W(CO)(6)}(2)](+)[F‐{Al(OR(F))(3)}(2)](−) (R(F)=C(CF(3))(3)) are reported along with their structural and spectroscopic characterization. The X‐ray structure shows that three carbonyl ligands from each M(CO)(6) fragment bend towards the silver atom with...
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| Yayımlandı: | Chemistry |
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| Asıl Yazarlar: | , , , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
John Wiley and Sons Inc.
2020
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7839444/ https://ncbi.nlm.nih.gov/pubmed/32964504 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003934 |
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