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Biocatalytic strategy for the highly stereoselective synthesis of CHF(2)-containing trisubstituted cyclopropanes

The difluoromethyl (CHF(2)) group has attracted significant attention in drug discovery and development efforts, owing to its ability to serve as fluorinated bioisostere of methyl, hydroxyl, and thiol groups. Herein, we report an efficient biocatalytic method for the highly diastereo- and enantiosel...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Carminati, Daniela M., Decaens, Jonathan, Couve-Bonnaire, Samuel, Jubault, Philippe, Fasan, Rudi
Format: Artigo
Langue:Inglês
Publié: 2021
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7969403/
https://ncbi.nlm.nih.gov/pubmed/33337576
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015895
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