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Biocatalytic strategy for the highly stereoselective synthesis of CHF(2)-containing trisubstituted cyclopropanes

The difluoromethyl (CHF(2)) group has attracted significant attention in drug discovery and development efforts, owing to its ability to serve as fluorinated bioisostere of methyl, hydroxyl, and thiol groups. Herein, we report an efficient biocatalytic method for the highly diastereo- and enantiosel...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Angew Chem Int Ed Engl
Main Authors: Carminati, Daniela M., Decaens, Jonathan, Couve-Bonnaire, Samuel, Jubault, Philippe, Fasan, Rudi
Format: Artigo
Jezik:Inglês
Izdano: 2021
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7969403/
https://ncbi.nlm.nih.gov/pubmed/33337576
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015895
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