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Biocatalytic strategy for the highly stereoselective synthesis of CHF(2)-containing trisubstituted cyclopropanes

The difluoromethyl (CHF(2)) group has attracted significant attention in drug discovery and development efforts, owing to its ability to serve as fluorinated bioisostere of methyl, hydroxyl, and thiol groups. Herein, we report an efficient biocatalytic method for the highly diastereo- and enantiosel...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Carminati, Daniela M., Decaens, Jonathan, Couve-Bonnaire, Samuel, Jubault, Philippe, Fasan, Rudi
Formato: Artigo
Idioma:Inglês
Publicado em: 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7969403/
https://ncbi.nlm.nih.gov/pubmed/33337576
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015895
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