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On The Nature of C(sp(3))-C(sp(2)) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides
The merger of photoredox and nickel catalysis has enabled the construction of quaternary centers. However, the mechanism, role of the ligand, and effect of the spin state for this transformation, and related Ni-catalyzed cross-couplings involving tertiary alkyl radicals in combination with bipyridin...
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| Опубликовано в: : | J Am Chem Soc |
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| Главные авторы: | , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2020
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7909746/ https://ncbi.nlm.nih.gov/pubmed/32195579 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c02355 |
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