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C(sp(3))–C(sp(2)) cross-coupling of alkylsilicates with borylated aryl bromides – an iterative platform to alkylated aryl- and heteroaryl boronates

The attractive field of iterative cross-coupling has seen numerous advances, although almost exclusively in the union of sp(2)-hybridized partners. Conspicuously absent from this useful synthetic manifold is the inclusion of sp(3)-hybridized pronucleophiles that can undergo transmetalation under mil...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Vara, Brandon A., Jouffroy, Matthieu, Molander, Gary A.
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2017
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5351799/
https://ncbi.nlm.nih.gov/pubmed/28451200
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc03236b
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