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Convergent Total Synthesis of Yaku’amide A

Total synthesis of the anticancer peptide natural product yaku’amide A is reported. Its β-tert hydroxy amino acids were prepared via regioselective aminohydroxylation involving a chiral mesyloxycarbamate reagent. Stereospecific construction of the E- and Z-ΔIle residues was accomplished via a one-po...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Cai, Yu, Ma, Zhiwei, Jiang, Jintao, Lo, Concordia C. L., Luo, Shi, Jalan, Ankur, Cardon, Joseph M., Ramos, Alexander, Moyá, Diego A., Joaquin, Daniel, Castle, Steven L.
Format: Artigo
Langue:Inglês
Publié: 2021
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7902439/
https://ncbi.nlm.nih.gov/pubmed/33336547
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014238
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