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Preparation of α-Perfluoroalkyl Ketones from α,β-Unsaturated Ketones via Formal Hydroperfluoroalkylation

[Image: see text] Formal hydroperfluoroalkylation of enones is achieved in a two-step process comprising conjugate hydroboration and subsequent radical perfluoroalkylation. The 1,4-hydroboration of the enone is conducted in the absence of any transition metal catalyst with catecholborane in 1,2-dich...

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Argitaratua izan da:Org Lett
Egile Nagusiak: Jana, Kalipada, Mizota, Isao, Studer, Armido
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: American Chemical Society 2021
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7901661/
https://ncbi.nlm.nih.gov/pubmed/33530687
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c04260
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