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Copper-Catalyzed Stille Cross-Coupling Reaction and Application in the Synthesis of the Spliceostatin Core Structure
An efficient palladium-free Stille cross-coupling reaction of allylic bromides and functionalized organostannylfUran using catalytic copper halide has been developed. The coupling reaction was optimized using CuI and low catalyst loading (down to 5 mol %). The reaction was conveniently carried out a...
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| Veröffentlicht in: | J Org Chem |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7900942/ https://ncbi.nlm.nih.gov/pubmed/32515594 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00976 |
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