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A Stable N‐Heterocyclic Silylene with a 1,1′‐Ferrocenediyl Backbone
The N‐heterocyclic silylene [{Fe(η(5)‐C(5)H(4)‐NDipp)(2)}Si] (1DippSi, Dipp=2,6‐diisopropylphenyl) shows an excellent combination of pronounced thermal stability and high reactivity towards small molecules. It reacts readily with CO(2) and N(2)O, respectively affording (1DippSiO(2))(2)C and (1DippSi...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898919/ https://ncbi.nlm.nih.gov/pubmed/33058389 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011691 |
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