A Stable N‐Heterocyclic Silylene with a 1,1′‐Ferrocenediyl Backbone

The N‐heterocyclic silylene [{Fe(η(5)‐C(5)H(4)‐NDipp)(2)}Si] (1DippSi, Dipp=2,6‐diisopropylphenyl) shows an excellent combination of pronounced thermal stability and high reactivity towards small molecules. It reacts readily with CO(2) and N(2)O, respectively affording (1DippSiO(2))(2)C and (1DippSi...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Weyer, Nadine, Heinz, Myron, Schweizer, Julia I., Bruhn, Clemens, Holthausen, Max C., Siemeling, Ulrich
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898919/
https://ncbi.nlm.nih.gov/pubmed/33058389
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011691
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