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Functionalization of α‐C(sp(3))−H Bonds in Amides Using Radical Translocating Arylating Groups
α‐C−H arylation of N‐alkylamides using 2‐iodoarylsulfonyl radical translocating arylating (RTA) groups is reported. The method allows the construction of α‐quaternary carbon centers in amides. Various mono‐ and disubstituted RTA‐groups are applied to the arylation of primary, secondary, and tertiary...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898318/ https://ncbi.nlm.nih.gov/pubmed/33215815 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013275 |
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