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Palladium-Catalyzed, Aminoquinoline-Directed Arylation of Phosphonamidate and Phosphinic Amide sp(3) C-H Bonds

Aminoquinoline-directed, palladium-catalyzed sp(3) C–H bond arylation in phosphonamidates and phosphinic amides is reported. The reaction employs Pd(OAc)(2) catalyst at 10 mol % loading and cesium phosphate or potassium carbonate base in 1,2-dichlorobenzene solvent. Directing group can be removed un...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Nguyen, Tung Thanh, Daugulis, Olafs
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5479433/
https://ncbi.nlm.nih.gov/pubmed/28394374
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc02063e
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