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Ligand Protonation Triggers H(2) Release from a Dinickel Dihydride Complex to Give a Doubly “T”‐Shaped Dinickel(I) Metallodiradical
The dinickel(II) dihydride complex (1(K)) of a pyrazolate‐based compartmental ligand with β‐diketiminato (nacnac) chelate arms (L(−)), providing two pincer‐type {N(3)} binding pockets, has been reported to readily eliminate H(2) and to serve as a masked dinickel(I) species. Discrete dinickel(I) comp...
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| 發表在: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , , , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
John Wiley and Sons Inc.
2020
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7894169/ https://ncbi.nlm.nih.gov/pubmed/33026170 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011494 |
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