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From Ylides to Doubly Yldiide-Bridged Iron(II) High Spin Dimers via Self-Protolysis

[Image: see text] A synthetic strategy for the preparation of novel doubly yldiide bridged iron(II) high spin dimers ([(μ(2)-C)FeL](2), L = N(SiMe(3))(2), Mesityl) has been developed. This includes the synthesis of ylide-iron(II) monomers [(Ylide)FeL(2)] via adduct formation. Subsequent self-protoly...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Yogendra, Sivathmeehan, Weyhermüller, Thomas, Hahn, Anselm W., DeBeer, Serena
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6750861/
https://ncbi.nlm.nih.gov/pubmed/31260277
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b01086
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