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Probing Physical Oxidation State by Resonant X‐ray Emission Spectroscopy: Applications to Iron Model Complexes and Nitrogenase

The ability of resonant X‐ray emission spectroscopy (XES) to recover physical oxidation state information, which may often be ambiguous in conventional X‐ray spectroscopy, is demonstrated. By combining Kβ XES with resonant excitation in the XAS pre‐edge region, resonant Kβ XES (or 1s3p RXES) data ar...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Castillo, Rebeca G., Hahn, Anselm W., Van Kuiken, Benjamin E., Henthorn, Justin T., McGale, Jeremy, DeBeer, Serena
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252016/
https://ncbi.nlm.nih.gov/pubmed/33497500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015669
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