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Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group

The development of straightforward synthesis of regio- and stereodefined alkenes with multiple aliphatic substituents under mild conditions is an unmet challenge owing to competitive β-hydride elimination and selectivity issues. Herein, we report the nickel-catalyzed intermolecular cross-dialkylatio...

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Dades bibliogràfiques
Publicat a:Nat Commun
Autors principals: Zhan, Yi-Zhou, Xiao, Nan, Shu, Wei
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2021
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7876002/
https://ncbi.nlm.nih.gov/pubmed/33568646
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-21083-w
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