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Coupling biocatalysis with high-energy flow reactions for the synthesis of carbamates and β-amino acid derivatives

A continuous flow process is presented that couples a Curtius rearrangement step with a biocatalytic impurity tagging strategy to produce a series of valuable Cbz-carbamate products. Immobilized CALB was exploited as a robust hydrolase to transform residual benzyl alcohol into easily separable benzy...

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Bibliografske podrobnosti
izdano v:Beilstein J Org Chem
Main Authors: Leslie, Alexander, Moody, Thomas S, Smyth, Megan, Wharry, Scott, Baumann, Marcus
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2021
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7871027/
https://ncbi.nlm.nih.gov/pubmed/33828617
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.17.33
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