Catalytic Chemoselective Sulfimidation with an Electrophilic [Co(III)(TAML)](−)‐Nitrene Radical Complex

The cobalt species PPh(4)[Co(III)(TAML(red))] is a competent and stable catalyst for the sulfimidation of (aryl)(alkyl)‐substituted sulfides with iminoiodinanes, reaching turnover numbers up to 900 and turnover frequencies of 640 min(−1) under mild and aerobic conditions. The sulfimidation proceeds...

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Publicado en:Chemistry
Autores principales: van Leest, Nicolaas P., van der Vlugt, Jarl Ivar, de Bruin, Bas
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839782/
https://ncbi.nlm.nih.gov/pubmed/32810326
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003566
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