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Insights into LiAlH(4) Catalyzed Imine Hydrogenation

Commercial LiAlH(4) can be used in catalytic quantities in the hydrogenation of imines to amines with H(2). Combined experimental and theoretical investigations give deeper insight in the mechanism and identifies the most likely catalytic cycle. Activity is lost when Li in LiAlH(4) is exchanged for...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Elsen, Holger, Langer, Jens, Ballmann, Gerd, Wiesinger, Michael, Harder, Sjoerd
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839755/
https://ncbi.nlm.nih.gov/pubmed/32869898
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003862
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