Calcium‐Catalyzed Arene C−H Bond Activation by Low‐Valent Al(I)

The low‐valent ß‐diketiminate complex ((DIPP)BDI)Al is stable in benzene but addition of catalytic quantities of [((DIPP)BDI)CaH](2) at 20 °C led to ((DIPP)BDI)Al(Ph)H ((DIPP)BDI=CH[C(CH(3))N‐DIPP](2), DIPP=2,6‐diisopropylphenyl). Similar Ca‐catalyzed C−H bond activation is demonstrated for toluene...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Brand, Steffen, Elsen, Holger, Langer, Jens, Grams, Samuel, Harder, Sjoerd
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6856855/
https://ncbi.nlm.nih.gov/pubmed/31465144
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908978
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