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Magnesium Cyanide or Isocyanide?
Preference for the binding mode of the CN(−) ligand to Mg (Mg−CN vs. Mg−NC) is investigated. A monomeric Mg complex with a terminal CN ligand was prepared using the dipyrromethene ligand (Mes)DPM which successfully blocks dimerization. While reaction of ((Mes)DPM)MgN(SiMe(3))(2) with Me(3)SiCN gave...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6856803/ https://ncbi.nlm.nih.gov/pubmed/31461208 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909511 |
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