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Cationic Functionalisation by Phosphenium Ion Insertion

The reaction of [Cp′′′Ni(η(3)‐P(3))] (1) with in situ generated phosphenium ions [RR′P](+) yields the unprecedented polyphosphorus cations of the type [Cp′′′Ni(η(3)‐P(4)R(2))][X] (R=Ph (2 a), Mes (2 b), Cy (2 c), 2,2′‐biphen (2 d), Me (2 e); [X](−)=[OTf](−), [SbF(6)](−), [GaCl(4)](−), [BAr(F)](−), [...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chemistry
Egile Nagusiak: Riesinger, Christoph, Dütsch, Luis, Balázs, Gábor, Bodensteiner, Michael, Scheer, Manfred
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: John Wiley and Sons Inc. 2020
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839539/
https://ncbi.nlm.nih.gov/pubmed/32996637
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003291
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