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Cationic Functionalisation by Phosphenium Ion Insertion
The reaction of [Cp′′′Ni(η(3)‐P(3))] (1) with in situ generated phosphenium ions [RR′P](+) yields the unprecedented polyphosphorus cations of the type [Cp′′′Ni(η(3)‐P(4)R(2))][X] (R=Ph (2 a), Mes (2 b), Cy (2 c), 2,2′‐biphen (2 d), Me (2 e); [X](−)=[OTf](−), [SbF(6)](−), [GaCl(4)](−), [BAr(F)](−), [...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7839539/ https://ncbi.nlm.nih.gov/pubmed/32996637 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003291 |
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