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Tuning the Proton‐Coupled Electron‐Transfer Rate by Ligand Modification in Catalyst–Dye Supramolecular Complexes for Photocatalytic Water Splitting

In view of the considerably high activation energy barrier of the O−O bond formation photocatalytic step in water oxidation, it is essential to understand if and how nonadiabatic factors can accelerate the proton‐coupled electron transfer (PCET) rate in this process to find rational design strategie...

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Publicat a:ChemSusChem
Autors principals: Yang, de Groot, Huub J. M., Buda, Francesco
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7821158/
https://ncbi.nlm.nih.gov/pubmed/32871047
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cssc.202001863
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