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Tuning the Proton‐Coupled Electron‐Transfer Rate by Ligand Modification in Catalyst–Dye Supramolecular Complexes for Photocatalytic Water Splitting

In view of the considerably high activation energy barrier of the O−O bond formation photocatalytic step in water oxidation, it is essential to understand if and how nonadiabatic factors can accelerate the proton‐coupled electron transfer (PCET) rate in this process to find rational design strategie...

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Bibliographic Details
Published in:ChemSusChem
Main Authors: Yang, de Groot, Huub J. M., Buda, Francesco
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7821158/
https://ncbi.nlm.nih.gov/pubmed/32871047
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cssc.202001863
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