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Proton Acceptor near the Active Site Lowers Dramatically the O–O Bond Formation Energy Barrier in Photocatalytic Water Splitting

[Image: see text] The O–O bond formation process via water nucleophilic attack represents a thermodynamic and kinetic bottleneck in photocatalytic water oxidation because of the considerably high activation free energy barrier. It is therefore of fundamental significance and yet challenging to find...

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Bibliografski detalji
Izdano u:J Phys Chem Lett
Glavni autori: Shao, Yang, de Groot, Huub J.M., Buda, Francesco
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2019
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6926955/
https://ncbi.nlm.nih.gov/pubmed/31763842
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.9b02914
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